Reaction Kinetics and Catalysis Letters

, Volume 52, Issue 2, pp 275–283 | Cite as

Silylation effect on the catalytic properties of FeZSM-11 in benzene oxidation to phenol

  • L. V. Piryutko
  • O. O. Parenago
  • E. V. Lunina
  • A. S. Kharitonov
  • L. G. Okkel
  • G. I. Panov
Article

Abstract

The outer surface of FeZSM-11 zeolite was selectively silylated without affecting the inner system of its channels. SiO2 deposition suppressed both the acidity and catalytic activity of the outer surface in mesitylene isomerization. Neither zeolite activity, nor its stability in N2O benzene oxidation to phenol have changed upon silylation. This fact gives evidence that the latter reaction proceeds primarily within the zeolite channels.

Keywords

Oxidation Physical Chemistry SiO2 Phenol Benzene 

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Copyright information

© Akadémiai Kiadó 1994

Authors and Affiliations

  • L. V. Piryutko
    • 1
  • O. O. Parenago
    • 2
  • E. V. Lunina
    • 2
  • A. S. Kharitonov
    • 1
  • L. G. Okkel
    • 1
  • G. I. Panov
    • 1
  1. 1.Boreskov Institute of CatalysisNovosibirskRussia
  2. 2.Moscow State UniversityMoscowRussia

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