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Catalytic properties of bismuth molybdate and its constituent oxides in methanol oxidation

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Abstract

The catalytic properties of Bi2O3, MoO3 and Bi2 (MoO4)3 in methanol oxidation are considered with respect to the binding energy of surface oxygen. MoO3 and Bi2(MoO4)3 with high binding energy of oxygen are characterized by good selectivity in the oxidation of alcohol to formaldehyde. However, in this case no correlation is observed between the variations in binding energy, activity and selectivity.

Abstract

Каталитические свойства Bi2O3, MoO3 и Bi2(MoO4)3 в реакции окисления метанола сопоставлены с энергией связи кислорода на поверхности, MoO3 и Bi2(MoO4)3 с высокой энергией связи кислорода избирательны при окислении спирта до формальдегида, однако в этом случае нет корреляции межды изменениями энергии связи, активности и селективности.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    B. I. Popov & V. N. Bibin

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  1. B. I. Popov
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  2. V. N. Bibin
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Popov, B.I., Bibin, V.N. Catalytic properties of bismuth molybdate and its constituent oxides in methanol oxidation. React Kinet Catal Lett 3, 337–341 (1975). https://doi.org/10.1007/BF02067776

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  • DOI: https://doi.org/10.1007/BF02067776

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