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Reaction Kinetics and Catalysis Letters

, Volume 6, Issue 1, pp 35–41 | Cite as

Kinetics of oxidative coupling of thiophene in the presence of Pd(OAc)2

  • I. V. Kozhevnikov
  • Yu V. Burov
  • K. I. Matveev
Article

Abstract

The kinetics of oxidative coupling of thiophene to bithiophene in the presence of Pd(OAc)2 in acetic acid solution has been studied at 60–80°C. The mechanism of the reaction is discussed.

Keywords

Acetic Physical Chemistry Acetic Acid Catalysis Acid Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Исследована кинетика окислительного сочетания тиофена в дитиенил под действием Pd (OAc)2 в HOAc при температуре 60–80°. Обсуждается механизм реакции.

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References

  1. 1.
    I.V. Kozhevnikov: React. Kinet. Catal. Lett.,4, 451 (1976).Google Scholar
  2. 2.
    R.A. Hoffman, S. Gronowitz: Arkiv Kemi,15, 45 (1960).Google Scholar
  3. 3.
    L. Eberson, L. Gomez-Gonzalez: Acta Chem. Scand.,27, 1249 (1973).Google Scholar
  4. 4.
    T. Onouchi, S. Matsuhira, N. Nagato: J. Chem. Soc. Japan, Chem. Ind. Chem., 1016 (1972).Google Scholar
  5. 5.
    R. Van Helden, G. Verberg: Recl. Trav. Chim. Pays-Bas,84, 1263 (1965).Google Scholar
  6. 6.
    J.M. Davidson, C. Triggs: J. Chem. Soc. (A). 1324 (1968).Google Scholar
  7. 7.
    E.W. Stern: Transition Metals in Homogeneous Catalysis, ed. by G.N. Schrauzer, p. 93. Dekker, New York 1971.Google Scholar
  8. 8.
    M. Kashima, H. Yoshimoto, H. Itatani: J. Catal.,29, 92 (1973).Google Scholar

Copyright information

© Akadémiai Kiadó 1977

Authors and Affiliations

  • I. V. Kozhevnikov
    • 1
  • Yu V. Burov
    • 1
  • K. I. Matveev
    • 1
  1. 1.Institute of CatalysisNovosibirskUSSR

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