Abstract
By IR and Raman spectroscopy it has been shown that excess MoO3 is bound molecularly on the surface of CdMoO4, presumably on sites of C2 and Ci symmetry. This increases the activity and selectivity of the catalyst in methanol oxidation to formaldehyde.
Abstract
Методами ИК, КР спектроскопии показано, что избыточный MoO3 закрепляется молекулярно на поверхности CdMoO4, вероятно в местах симметрии C2 и Ci. Это приводит к повышению каталитической активности и избирательности катализатора в реакции окисления метанола до формальдегида.
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Yurchenko, E.N., Shkuratova, L.N., Kustova, G.N. et al. Influence of excess MoO3 in a non-stoichiometric cadmium-molybdenum catalyst on the catalytic properties in methanol oxidation. React Kinet Catal Lett 6, 9–15 (1977). https://doi.org/10.1007/BF02067733
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DOI: https://doi.org/10.1007/BF02067733