Abstract
The activation parameters of the base catalyzed reaction of triphenylsilane with water, in aqueous acetonitrile (ACN), indicate that the structure changes in the mixture play a determining role in the variations of the reaction rate. The activity coefficient of the catalyst OH− in these media is also discussed in terms of solvent effect.
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Tondeur, J.J., Borghese, A. & Vandendunghen, G. Alkaline solvolysis of triphenylsilane, part 3. Activation parameters in water/acetonitrile mixtures. React Kinet Catal Lett 49, 241–249 (1993). https://doi.org/10.1007/BF02067688
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DOI: https://doi.org/10.1007/BF02067688