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Dehydrocyclization of 1-heptene-1-14C over chromia on non-acidic alumina

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Abstract

The dehydrocyclization of 1-heptene-1-14C has been investigated over a chromia on “nonacidic” alumina catalyst with the aim of determining the14C distribution in the ring of the toluene product. As high as 80% of the14C was consistently found in the methyl position as predicted for direct six-carbon ring formation.

Abstract

Реакция дегидроциклизации 1-гептена-1-C14 была исследована на окиси хрома, нанесенной на некислую окись алюминия, с целью определения распределения C14 в кольце толуольного продукта. Около 80%-ов всего C14 было обнаружено в положении метила, что указывает на непосредственное образование шестичленного углеродного кольца.

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Authors and Affiliations

  1. Potomac State College of West Virginia University, 26726, Keyser, West Virginia, USA

    B. H. Davis & P. Fejes

  2. Radiochemistry Department, “József Attila” University, Szeged, Hungary

    B. H. Davis & P. Fejes

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  1. B. H. Davis
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  2. P. Fejes
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Davis, B.H., Fejes, P. Dehydrocyclization of 1-heptene-1-14C over chromia on non-acidic alumina. React Kinet Catal Lett 1, 183–188 (1974). https://doi.org/10.1007/BF02067538

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  • DOI: https://doi.org/10.1007/BF02067538

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