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Reaction Kinetics and Catalysis Letters

, Volume 10, Issue 1, pp 1–6 | Cite as

Mechanism of Pd(II) reduction with benzene in sulfuric acid. π-Complexes of benzene with Pd(II) and Pd(I)

  • E. S. Rudakov
  • V. L. Lobachev
  • R. I. Rudakova
Article

Abstract

π-complexes of Pd(II) and Pd(I) with benzene in sulfuric acid have been detected via NMR and electronic spectra. Their stability constants and chemical shifts have been determined and compared with the Ag(I) benzene complex.

Keywords

Physical Chemistry Benzene Catalysis Sulfuric Acid Chemical Shift 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

На основании ПМР — и электронных спектров обнаружены п-комплексы PdII-бензол и PdI-бензол в серной кислоте. Определены их константы устойчивости и химические сдвити в сравнении с комплексом AgI-бензоп.

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References

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    E. S. Rudakov, R. I. Rudakova: Dokl. Akad. Nauk SSSR,218, 1337 (1974).Google Scholar
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    J. M. Davidon S. Triggs: J. Chem. Soc. (A). 1324 (1968).Google Scholar
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    G. Allegra, A. Immirzi, L. Porri: J Amer. Chem. Soc.,87, 1394 (1965).Google Scholar
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    L. J. Andrews, R. M. Keefer: J. Amer. chem. Soc.,71, 3644 (1949).Google Scholar

Copyright information

© Akadémiai Kiadó 1979

Authors and Affiliations

  • E. S. Rudakov
    • 1
  • V. L. Lobachev
    • 1
  • R. I. Rudakova
    • 1
  1. 1.Institute of Physical Organic and Carbon ChemistryDonetskUSSR

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