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On the mechanism of arylation of ethylene by palladium(II)

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Abstract

The phenylation of ethylene with benzene under the effect of palladium acetate at [C2H4] ≫ [Pd(OAc)2] has been found to give styrene and trans-stilbene via parallel rather than consecutive reactions. The data obtained indicate that styrene and stilbene are formed through the same intermediate. The reaction mechanism is discussed.

Abstract

Установлено, что при фенилировании этилена бензолом под действием ацетата палладия при [C2H4]≫[Pd(OAc)2] стирол и транс-стильбен образуются в параллеьных реакциях. Полученные данные позволяют полагать, что стирол и стильбен получаются через один интермедат. Обсуждается механизм реакции.

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References

  1. Y. Fujiwara, I. Moritani, S. Danno, R. Asano, S. Teranishi: J. Amer. Chem. Soc.,91, 7166 (1969).

    Google Scholar 

  2. I. Moritani, Y. Fujiwara: Synthesis, 524 (1973).

  3. N. B. Shitova, K. I. Matveev, L. I. Kuznetsova: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim.,1, 25 (1973).

    Google Scholar 

  4. J. M. Davidson, C. Triggs: J. Chem. Soc. A, 1324 (1968)

  5. N. B. Shitova, L. I. Kuznetsova, K. I. Matveev: Kinet. Katal.,15, 72 (1974).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    I. V. Kozhevnikov & K. I. Matveev

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  1. I. V. Kozhevnikov
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  2. K. I. Matveev
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Kozhevnikov, I.V., Matveev, K.I. On the mechanism of arylation of ethylene by palladium(II). React Kinet Catal Lett 5, 61–65 (1976). https://doi.org/10.1007/BF02067434

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  • DOI: https://doi.org/10.1007/BF02067434

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