Abstract
Propylene adsorption and transformation on metals of the Pt group have been studied. Propylene chemisorption decreases in the following series: Rh>Pt>Ir>Ru>Pd and it is accompanied by the formation of π-allyl and π-complexes. The lowest conversions of propylene are observed on Pt, next are Ru, Rh, Ir and Pd.
Abstract
Изучена адсорбция и превращение пропилена на металлах Pt-группы. Показано, что хемосорбция пропилена падает в ряду: Rh>Pt>Ir>Ru>Pd и протекает с образованием π-аллильного и π-комплекса. Наименьшим превращениям пропилен подвергается на Pt, затем идут Ru, Rh, Ir, Rd.
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Beketaeva, L.A., Zakumbaeva, G.D. & Kalanova, S.M. Adsorption of propylene on platinum-group metals. React Kinet Catal Lett 5, 15–20 (1976). https://doi.org/10.1007/BF02067427
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DOI: https://doi.org/10.1007/BF02067427