Abstract
Changes in the IR spectra of nitrogen oxides and ammonia adsorbed on Al2O3 caused by UV irradiation indicate that in the presence of gaseous or liquid (−196°C) O2 photooxidation takes place, resulting mostly in the formation of surface NO −3 ions.
Abstract
Вызываемые УФ-облучением изменения в ИК-спектрах окислов азота и аммиака, адсорбированных на Al2O3, свидетельствуют о том, что в присутствии газообразного или жидкого (при−196°C) кислорода происходит фотоокисление адсорбированных молекул с образованием преимущественно поверхностных ионов NO −3 .
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References
V. N. Filimonov: Dokl. Akad. Nauk SSSR,158, 1408 (1964).
V.N. Filimonov: Elementary Photoprocesses in Molecules, Ed. B. Neporent, p. 248. C. B. New York 1968.
N. D. Parkyns: Proc. 5th Int. Congr. Catal. Vol. 1, p. 255 Amsterdam 1973.
D. V. Pozdnyakov, V. N. Filimonov: Adv. Mol. Relaxation Proc.5, 55 (1973).
A. V. Nogin, A. V. Alekseyev, V. N. Filimonov: Zh. Fiz. Khim.,50, 183 (1976).
Chien-Chung Chao, J. H. Lunsford: J. Amer. Chem. Soc.,93, 71 (1971).
K. Nakamoto: Infrared Spectra of Inorganic and Coordination Compounds. Wiley, New York 1968.
A. A. Tsyganenko, D. V. Pozdnyakov, V. N. Filimonov: J. Mol. Struct.29, 299 (1975).
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Alekseev, A.V., Pozdnyakov, D.V., Tsyganenko, A.A. et al. Infrared study of photooxidation of nitrogen oxides and ammonia adsorbed on alumina. React Kinet Catal Lett 5, 9–14 (1976). https://doi.org/10.1007/BF02067426
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DOI: https://doi.org/10.1007/BF02067426