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Preparation and properties of supported vanadium-phosphorus catalysts studied by chemical analysis and ESR

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Abstract

The preparation of vanadium-phosphorus catalysts is described, showing the considerable influence of phosphorus on the concentration of V4+ ions. The oxidation properties were studied by chemical analysis and electron spin resonance. Moreover, ESR spectra show a strong influence of moisture on the structure of the catalysts.

Abstract

Было описано получение ванадий-фосфорных катализаторов, для которых было обнаружено значительное влияние фосфора на концентрацию ионов V+4. Окислительные свойства катализаторов были исследованы химическим анализом, а также с помощью ЭПР. Спектры ЭПР, помимо этого, указывают на эначительное влияние влаги на структуру катализатора.

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References

  1. E. V. Rozhkova, S. V. Gerei, Ya. B. Gorokhovatskii: Kinet. Katal.,15, 964, (1974).

    Google Scholar 

  2. M. Nakamura, K. Kawai, Y. Fujiwara: J. Catal.,34, 345, (1974).

    Google Scholar 

  3. S. Yoshida, N. Tamura, S. Teranishi, K. Tarama: Bull. Inst. Chem. Res. Kyoto Univ.,47, 1029, (1969).

    Google Scholar 

  4. T. Otaki: 2nd Japanese-Soviet Seminar on Catalysis, Tokyo 1973.

  5. R. Fricke, H. G. Jerschkewitz, G. Öhlmann: J. Catal. (to be published)

  6. V. V. Pigulevski, A. L. Joanesova, E. A. Makhova, V. M. Trofimov Z. Prikl. Khim.,37, 1898, (1964).

    Google Scholar 

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Authors and Affiliations

  1. Central Institute of Physical Chemistry, Academy of Sciences of the GDR, Berlin-Adlershof

    R. Fricke & H. -G. Jerschkewitz

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  1. R. Fricke
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  2. H. -G. Jerschkewitz
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Fricke, R., Jerschkewitz, H.G. Preparation and properties of supported vanadium-phosphorus catalysts studied by chemical analysis and ESR. React Kinet Catal Lett 5, 1–8 (1976). https://doi.org/10.1007/BF02067425

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  • DOI: https://doi.org/10.1007/BF02067425

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