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Reaction Kinetics and Catalysis Letters

, Volume 56, Issue 1, pp 121–127 | Cite as

Catalytic hydrogen transfer over MgO, VII. Dehydrogenation of pinocarveol and pinocampheol

  • M. Glinski
  • J. Kijenski
  • J. Gibka
  • J. Góra
Article

Abstract

The dehydrogenation of pinocarveol to pinocarvone and pinocampheol to pinocamphone over MgO by hydrogen transfer to aldehydes and ketones as acceptors has been studied. The yields of pinocarvone formed from the unsaturated alcohol did not exceed 10 mol%, while pinocampheol was dehydrogenated to the desired ketone with yields in the range of 40 mol%.

Keywords

Hydrogen Alcohol Physical Chemistry Catalysis Aldehyde 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Mitsubishi Chemical Industries Co. Ltd., Jpn Kokai Tokkyo Koho 81 30.905, Chem. Abs.,95, 37124f (1981).Google Scholar
  2. 2.
    S. Arctander:Perfume and Flavor Chemicals, Vol. 2, 2624–2622, Author Monteclair, New York 1969.Google Scholar
  3. 3.
    N. C. Shah:Indian Perfum.,35, 49 (1991).Google Scholar
  4. 4.
    E. Gildemeister, F. Hoffmann: (ed. W. Treibs).Die Ätherischen Öle, Vol. III c, p. 285. Akademie Verlag, Berlin 1960.Google Scholar
  5. 5.
    P. C. Traas: inFragrance Chemistry (ed. E. T. Theimer), p. 179. Academic Press, New York 1982.Google Scholar
  6. 6.
    A. Kover, H. R. Hoffmann:Tetrahedron,44, 6831 (1988).CrossRefGoogle Scholar
  7. 7.
    J. Kijeński J., M. Gliński, M. Czarnecki, R. Derlacka, V. Jarzyna:Stud. Surf. Sci. Catal.,78, 631 (1993).Google Scholar
  8. 8.
    J. Kijeński, S. Malinowski:J. Chem. Soc. Faraday Trans. I,74, 250 (1978).CrossRefGoogle Scholar
  9. 9.
    M. Gliński, J. Kijeński, J. Ruszczyński:React. Kinet. Catal. Lett.,54, 1 (1995).CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1995

Authors and Affiliations

  • M. Glinski
    • 1
  • J. Kijenski
    • 1
  • J. Gibka
    • 1
  • J. Góra
    • 2
  1. 1.Chemical Faculty, Laboratory of Catalytic SynthesisWarsaw Technical University (Politechnika)WarsawPoland
  2. 2.Institute of General Food ChemistryTechnical University of LódźLódźPoland

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