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Catalytic hydrogen transfer over MgO, VII. Dehydrogenation of pinocarveol and pinocampheol

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Abstract

The dehydrogenation of pinocarveol to pinocarvone and pinocampheol to pinocamphone over MgO by hydrogen transfer to aldehydes and ketones as acceptors has been studied. The yields of pinocarvone formed from the unsaturated alcohol did not exceed 10 mol%, while pinocampheol was dehydrogenated to the desired ketone with yields in the range of 40 mol%.

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Article Open access 02 December 2021

Baoxin Zhang, Dilver Peña Fuentes & Armin Börner

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Authors and Affiliations

  1. Chemical Faculty, Laboratory of Catalytic Synthesis, Warsaw Technical University (Politechnika), Koszykowa 75, 00-662, Warsaw, Poland

    M. Glinski, J. Kijenski & J. Gibka

  2. Institute of General Food Chemistry, Technical University of Lódź, Stefanowskiego 6/10, 90-924, Lódź, Poland

    J. Góra

Authors
  1. M. Glinski
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  2. J. Kijenski
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  3. J. Gibka
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  4. J. Góra
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Glinski, M., Kijenski, J., Gibka, J. et al. Catalytic hydrogen transfer over MgO, VII. Dehydrogenation of pinocarveol and pinocampheol. React Kinet Catal Lett 56, 121–127 (1995). https://doi.org/10.1007/BF02066958

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  • DOI: https://doi.org/10.1007/BF02066958

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