Catalytic hydrogen transfer over MgO, VII. Dehydrogenation of pinocarveol and pinocampheol
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The dehydrogenation of pinocarveol to pinocarvone and pinocampheol to pinocamphone over MgO by hydrogen transfer to aldehydes and ketones as acceptors has been studied. The yields of pinocarvone formed from the unsaturated alcohol did not exceed 10 mol%, while pinocampheol was dehydrogenated to the desired ketone with yields in the range of 40 mol%.
KeywordsHydrogen Alcohol Physical Chemistry Catalysis Aldehyde
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