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Polymerization of benzyl alcohol and its derived compounds with an ion exchange resin

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Abstract

Benzyl alcohol, benzyl chloride and dibenzyl ether polymerize in certain conditions in the presence of ion exchange resins in the H+ form to give a polymer of the general formula (C6H4CH2)n. Independently of the reactant, this result allows to establish reaction mechanism based solely on the acid-base equilibrium in the Brönsted or Lewis meaning and independently of the catalyst type: sulfuric acid, stannic chloride or ion exchange resin.

Abstract

Бензиловый спирт, хлористый бензил и дибензиловый эфир полимеризуются в определенных условиях в присутствии ионообменной смолы в форме H+, давая при этом полимер с общей формулой (−C6H4CH2−)n. Независимо от реактивности, этот результат позволяет установить реакционный механизм, основанный на кислотно-основном равновесии по Брёнстэду или Ляюису, для любого типа катализатора: серная кислота, четыреххло ристое олово или ионообменная смола.

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References

  1. F. Fournet, A. Doucet, G. Doucet-Baudry, J. L. Janier Dubry: J. Chem. Research (S), p. 91 1980, and (M), p. 1001–1030. 1980.

  2. F. Fournet: Thèse Sciences, Besançon, France, 1979, N0 92.

  3. J. L. Janier-Dubry: Bull. Soc. Chim. Fr.,7–8, 1573 (1975).

    Google Scholar 

  4. J. L. Janier Dubry, C. Devin: Bull. Soc. Chim. Fr.,7–8, 1578 (1975).

    Google Scholar 

  5. G. Illari: Gazz. Chim. Ital.,78, 904 (1958).

    Google Scholar 

  6. G. Montaudo, F. Bottino, S. Caccamese: Ann. Chim. (Roma),57, (8–9), 992 (1967).

    Google Scholar 

  7. D. B. V. Parker, W. G. Daviez, K. D. South: J. Chem. Soc., (B),5, 471 (1967).

    Google Scholar 

  8. J. N. Brönsted: Rec. Trav. Chim.,42, 718 (1923).

    Google Scholar 

  9. G. N. Lewis: J. Franklin Inst.,226, 293 (1938).

    Google Scholar 

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Authors and Affiliations

  1. Laboratoire de Chimie Moléculaire et de Catalyse Departement de Chimie Faculte des Sciences et Techniques de Sfax, B. P., W Sfax, Tunisie

    T. M'Hiri, Ch. Catusse, R. Catusse & J. L. Janier Dubry

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  1. T. M'Hiri
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  2. Ch. Catusse
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  3. R. Catusse
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  4. J. L. Janier Dubry
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M'Hiri, T., Catusse, C., Catusse, R. et al. Polymerization of benzyl alcohol and its derived compounds with an ion exchange resin. React Kinet Catal Lett 22, 425–428 (1983). https://doi.org/10.1007/BF02066216

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  • DOI: https://doi.org/10.1007/BF02066216

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