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Selective hydrogenation of benzoyl chloride over supported palladium catalysts

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Abstract

Liquid-phase hydrogenation of benzoyl chloride has been studied using palladium supported over inorganic (Al2O3, C, CaCO3) and polymeric (nylon, stirene-vinylbenzene) materials. The reaction is zero order with respect to benzoyl chloride. The rate of reaction has been found to be dependent on the support used. It is suggested that the lower reaction rate found on the polymeric support is related to the presence of palladium not completely reduced.

Abstract

Жидкофазное гидрирование бензоилхлорида было исследовано на палладии, нанесенном на неорганические (Al2O3, C, CaCO3) и полимерные (найлон, полистирол) материалы. Реакция имеет нулевой порядок по хлористому бензоилу. Скорость реакции зависит от используемого носителя. Полагается, что наблюдаемое уменьшение скорости на полимерном носителе связано с присутствием неполностью восстановленного палладия.

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Authors and Affiliations

  1. Istituto di Chimica Industriale, Università di Messina, 98100, Messina, (Italy)

    Z. Poltarzewsky, P. Staiti & N. Giordano

  2. Istituto CNR di Ricerche sui Metodi e Processi Chimici per la Trasformazione e l'Accumulo del-l'Energia, 98013, Pistunina-Messina, (Italy)

    S. Galvagno, P. Antonucci & A. Rositani

Authors
  1. Z. Poltarzewsky
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  2. S. Galvagno
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  3. P. Staiti
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  4. P. Antonucci
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  5. A. Rositani
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  6. N. Giordano
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Poltarzewsky, Z., Galvagno, S., Staiti, P. et al. Selective hydrogenation of benzoyl chloride over supported palladium catalysts. React Kinet Catal Lett 22, 383–389 (1983). https://doi.org/10.1007/BF02066209

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  • DOI: https://doi.org/10.1007/BF02066209

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