Abstract
A kinetic study of the oxidation of phenanthrene and acenaphthene by phenyliodosoacetate (PIA) in aqueous acetic acid-perchloric acid medium is reported. The order with respect to oxidant, substrate(s) and acid is each unity. A suitable mechanism is proposed and a corresponding rate law derived.
Abstract
Описывается кинетическое исследование окисления фенантрена и фенилиодозоацетата в среде водной, уксусной и перхлорной кислоты. Порядок по отношению к окислителю, субстрату (ам) и кислоте каждый равен единице. Приводится вероятный механизм и выводится соответствующее у равнение скорости.
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Radhakrishnamurti, P.S., Panda, B.K. Pathways in aromatic oxidations by PIA. React Kinet Catal Lett 22, 379–382 (1983). https://doi.org/10.1007/BF02066208
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DOI: https://doi.org/10.1007/BF02066208