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Sulfurization of molybdena-alumina catalysts

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Abstract

Sulfurization of molybdena-alumina catalysts has been found to depend on the configuration of their molybdenum compounds. At a sulfurization temperature of 673 K, S/Mo ∼ 2 and ∼ 1 for Mo compounds of octahedral [Mo(O)] and tetrahedral [Mo(T)] configuration, respectively.

Abstract

Сульфидируемость алюмомолибденовых катализаторов зависит от структуры соединений молибдена в ниш. При температуре сульфидирования 673 К отношение Ѕ/Мо достигает 2 для соединений Мо октаэдрической конфигу рации [Мо(О)] и 1 для соединений Мо тетраэдрической конфигу рации [Мо(Т)].

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References

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Kim, E.K., Timashkova, B.V., Khankhasaev, Y.I. et al. Sulfurization of molybdena-alumina catalysts. React Kinet Catal Lett 22, 331–333 (1983). https://doi.org/10.1007/BF02066197

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  • DOI: https://doi.org/10.1007/BF02066197

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