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Molecular isotope exchange of14CO in surface carbonyl complexes of rhodium

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Abstract

Molecular isotope exchange of CO with14CO for Rh6(CO)16/Sn(II)−SiO2, Rh6(CO)16/Al2O3, Rh(I)(CO)2/Al2O3, Rh4(CO)12/Al2O3 carbonyl complexes of rhodium has been studied. Estimates of the activation energies and a mechanism of the CO exchange are suggested.

Abstract

Дла систем, содержащих поверхностные карбонильные комплексы родия (Rh6(CO)16/Sn(II)−SiO2, Rh6(CO)16/Al2O3, RhI(CO)2/Al2O3, Rh4(CO)12/Al2O3), исследован молекулярный изотопный обмен окиси углерода с14CO. Оценены знергии активации и сделаны предположения о возможных механизмах обмена CO в поверхностных комплексах родия.

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Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    L. I. Bulgakova, V. L. Kuznetsov, Yu. I. Yermakov & L. A. Sazonov

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  1. L. I. Bulgakova
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  2. V. L. Kuznetsov
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  3. Yu. I. Yermakov
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  4. L. A. Sazonov
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Bulgakova, L.I., Kuznetsov, V.L., Yermakov, Y.I. et al. Molecular isotope exchange of14CO in surface carbonyl complexes of rhodium. React Kinet Catal Lett 22, 259–264 (1983). https://doi.org/10.1007/BF02066184

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  • DOI: https://doi.org/10.1007/BF02066184

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