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Hyperfine Interactions

, Volume 19, Issue 1–4, pp 785–791 | Cite as

Formation of muonium substituted free radicals

  • E. Roduner
Mounium Radical Formation and Chemical Reactions

Abstract

μSR experiments with mixtures of benzene with cyclohexane, 2,3-dimethyl-1,3-butadiene and carbontetrachloride allow the conclusion that the direct muonic precursor of the muonic cyclohexadienyl radical is thermal muonium. In neat benzene it has a life time of 10 ps and disappears by the addition reaction. Muonium is formed within about 1 ps by combination of the positive muon with an electron near the end of the track of the thermalizing muon.

Keywords

Thin Film Benzene Free Radical Cyclohexane Life Time 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. [1]
    E. Roduner and H. Fischer, Chem. Phys.54 (1981) 261Google Scholar
  2. [2]
    J.H. Brewer, F.N. Gygax and D.G. Fleming, Phys. Rev.A8 (1973) 77; J.H. Brewer, K.M. Crowe, F.N. Gygax, R.F. Johnson, D.G. Fleming, and A. Schenck, Phys. Rev.A9 (1974) 495Google Scholar
  3. [3]
    P.W. Percival and J. Hochmann, Hyperfine Interactions6 (1979) 421Google Scholar
  4. [4]
    S.F.J. Cox, A. Hill, and R. deRenzi, J. Chem. Soc., Faraday Trans. I,78 (1982) 2975Google Scholar
  5. [5]
    P.W. Percival, Hyperfine Interactions8 (1981) 315Google Scholar
  6. [6]
    D.C. Walker, Hyperfine Interactions8 (1981) 329Google Scholar
  7. [7]
    E. Roduner, G.A. Brinkman and P.W.F. Louwrier, Chem. Phys.73 (1982) 117Google Scholar
  8. [8]
    E. Roduner, G.A. Brinkman, and P.W.F. Louwrier, Hyperfine Interactions17–19 (1984) 803Google Scholar
  9. [9]
    E. Roduner and B.C. Webster, J. Chem. Soc., Faraday Trans. I,79 (1983) 1939Google Scholar
  10. [10]
    E. Roduner, W. Strub, P. Burkhard. J. Hochmann, P.W. Percival, H. Fischer. M.J. Ramos, and B.C. Webster, Chem. Phys.67 (1982) 275Google Scholar
  11. [11]
    M. Anbar, Farhatazziz and A.B. Ross, in Selected Specific Rates of Reactions of Transients from Water in Aqueous Solution. II Hydrogen Atom (NSRDS, NBS-51, Washington, 1975)Google Scholar
  12. [12]
    Y.C. Jean, J.H. Brewer, D.G. Fleming, D.M. Garner, R.J. Mikula, L.C. Vaz, and D.C. Walker, Chem. Phys. Letters57 (1978) 293Google Scholar
  13. [13]
    Y. Ito, B.W. Ng, Y.C. Jean, and D.C. Walker, Can. J. Chem.58 (1980) 2395Google Scholar
  14. [14]
    E. Roduner, Hyperfine Interactions17–19 (1984) 793Google Scholar
  15. [15]
    J.A. Kerr, and M.J. Parsonage, in Evaluated Kinetic Data on Gas Phase Addition Reactions (Butterworths, London, 1972)Google Scholar
  16. [16]
    J.W. Hunt, Adv. Radiat. Chem.5 (1976) 185Google Scholar
  17. [17]
    Y.C. Jean, B.W. Ng, J.H. Brewer, D.G. Fleming, and D.C. Walker, J. Phys. Chem.85 (1981) 451Google Scholar
  18. [18]
    J.M. Warman, K.D. Asmus, and R.H. Schuler, Adv. Chem. Series82 (1968) 25Google Scholar
  19. [19]
    E. Roduner, unpublished resultsGoogle Scholar
  20. [20]
    G. Wikander and O.E. Mogensen, Chem. Phys.72 (1982) 407Google Scholar
  21. [21]
    G.W. Klein and R.H. Schuler, J. Phys. Chem.77 (1973) 978Google Scholar
  22. [22]
    S.J. Rzad, P.P. Infelta, J.M. Warman, and R.H. Schuler, J. Chem. Phys.52 (1970) 3971Google Scholar
  23. [23]
    A.O. Allen, T.E. Gangwer, and R.A. Holroyd, J. Phys. Chem.79 (1975) 25Google Scholar
  24. [24]
    P.W. Percival, J. Chem. Phys.72 (1980) 2901Google Scholar

Copyright information

© J.C. Baltzer AG, Scientific Publishing Company, and Yamada Science FoundationJ.C. Baltzer AG, Scientific Publishing Company, and Yamada Science Foundation 1984

Authors and Affiliations

  • E. Roduner
    • 1
  1. 1.Physikalisch-Chemisches Institut der Universität ZürichZürichSwitzerland

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