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Reaction Kinetics and Catalysis Letters

, Volume 13, Issue 4, pp 401–406 | Cite as

Studies of the composition and catalytic properties of supported catalysts prepared through halide-substituted titanium and zirconium benzyl complexes

  • G. A. Nesterov
  • V. A. Zakharov
  • Yu. I. Yermakov
  • K. -H. Thiele
  • M. Schlegel
  • H. Drevs
Article

Abstract

Composition and catalytic properties in ethylene polymerization of supported systems prepared via the interaction of Ti(CH2C6H5)3X (X=F, Cl, Br) and Zr(CH2C6H5)2Cl2 complexes with silica and alumina have been studied. Halide addition to benzyl complexes decreases the polymer molecular mass.

Keywords

Polymer Alumina Ethylene Titanium Physical Chemistry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Исследован состав и каталитические свойства в полимеризации этилена нанесённых систем, полученных при взаимодействии комплексов состава Ti(CH2C6H5)3X (X=F, Cl, Br) и Zr(CH2C6H5)2Cl2 с SiO2 и Al2O3. Показано, что введение галоида в состав бензильных комплексов приводит к снижению молекулярной массы полимера.

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Copyright information

© Akadémiai Kiadó 1980

Authors and Affiliations

  • G. A. Nesterov
    • 1
  • V. A. Zakharov
    • 1
  • Yu. I. Yermakov
    • 1
  • K. -H. Thiele
    • 2
  • M. Schlegel
    • 2
  • H. Drevs
    • 2
  1. 1.Institute of CatalysisNovosibirskUSSR
  2. 2.T. H., “Carl Schorlemmer”Leuna-MerseburgDDR

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