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Reaction Kinetics and Catalysis Letters

, Volume 18, Issue 3–4, pp 357–361 | Cite as

Kinetics and mechanism of OsO4 catalyzed oxidation of maleic, fumaric, cinnamic and acrylic acids by acid bromate

  • P. S. Radhakrishnamurti
  • J. K. Panda
Article
  • 27 Downloads

Abstract

The title reactions are zero order in bromate, first order in both substrate and catalyst. The order of reactivity is cinnamic acid>acrylic acid>fumaric acid>maleic acid. A plausible mechanism is discussed.

Keywords

Oxidation Physical Chemistry Catalysis Acrylic Acid Maleic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Заглавная реакция имеет нулевой порядок по бромату, первый порядок по субстрату и катализатору. Порядок реактивности следующий: коричная кислота> акриловая кислота>фумаровая кислота>малеиновая кислота. Обсуждается вероятный механизм.

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Copyright information

© Akadémiai Kiadó 1981

Authors and Affiliations

  • P. S. Radhakrishnamurti
    • 1
  • J. K. Panda
    • 1
  1. 1.Department of ChemistryBerhampur UniversityBerhampurIndia

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