Reaction Kinetics and Catalysis Letters

, Volume 16, Issue 2–3, pp 265–270 | Cite as

Selective hydrogenation of dehydrolinalool and dehydrolinalyl acetate to linalool and linalyl acetate

  • A. M. Pak
  • O. I. Kartonozhkina
  • A. P. Pogorelskii
  • E. M. Tsai
  • D. V. Sokolskii
Article

Abstract

Hydrogenation of dehydrolinalool and dehydrolinalyl acetate on 0.5% Pd/Al2O3 in C2–C5 alcohols of various structure has been studied at atmospheric and higher pressures of hydrogen. It is shown that the differences in selectivity of hydrogenation of dehydrolinalool to linalool and of dehydrolinalyl acetate to linalyl acetate is due to peculiarities in their structure.

Keywords

Hydrogenation Alcohol Acetate Physical Chemistry Catalysis 

Abstract

Изучено гидрирование дегидролиналоола и дегидролиналилацетата на 0,5% Pd/Al2O3 в спиртах C2–C5 раеличного строения при атмосферном и повышенном давлениях водорода. Показано, что различие в селективности гидрирования дегидролиналоола в линалоол и дегидролиналидацетата в линалилацеетат связано с особенностями их строения.

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Copyright information

© Akadémiai Kiadó 1981

Authors and Affiliations

  • A. M. Pak
    • 1
  • O. I. Kartonozhkina
    • 1
  • A. P. Pogorelskii
    • 1
  • E. M. Tsai
    • 1
  • D. V. Sokolskii
    • 1
  1. 1.Institute of Organic Catalysis and ElectrochemistryAlma-AtaUSSR

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