Abstract
The conditions of the Turing structures arising in the model of reaction-diffusion bromate-ferroin-bromomalonic acid system are studied. The existence of Turing structures is possible if the diffusion coefficients of HBrO2 and Br− are less than that of ferriin. It is shown, that the effective diffusion of HBrO2 and Br− can be strongly retarded in comparison with that of ferriin in the gel filtration chromatographic medium without the considerable change of the chemical kinetics of the reaction. It shows the possibility to obtain the Turing structures under conducting this oscillating reaction in the layer of chromatographic gel.
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References
A. Turing, Phil. Trans. R. Soc. London. Ser. B, 237, 37 (1952).
G. Nicolis, and I. Prigogine, Self-Organization in Non-Equilibrium Systems, Wiley, New York, 1977.
J. A. Vastano, J. E. Pearson, W. Horstemke, and H. L. Swinney, J. Chem. Phys. 88, 6175 (1988).
P. Borckmans, G. Dewel D. Walgraef, and Y. Katayama, J. Stat. Phys., 48, 1031 (1987).
P. K. Becker, and R. J. Field, J. Phys. Chem. 89, 118 (1985).
A. M. Zhabotinsky, and A. B. Rovinsky, J. Stat. Phys., 48, 959 (1987).
A. B. Rovinsky, J. Phys. Chem. 91 4606 (1987).
J. E. Pearson, and W. Horstemke, J. Chem. Phys., 90, 1588 (1989).
A. B. Rovinsky, and A. M. Zhabotinsky, J. Phys. Chem. 88, 6081 (1984).
A. B. Rovinsky, and A. M. Zhabotinsky, in Fundamental Research in Chemical Kinetics, A. E. Shilov, Ed. Gordon and Breach, London, 1986.
J. Tyson, in Oscillations and Traveling Waves in Chemical Systems, R. J. Field, and M. Burger, Eds., Wiley, New York, 1985.
L. R. Snyder, and J. J. Kirkland, Eds., Introduction to Modern Liquid Chromatography, Wiley, New York, 1979.
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Zhabotinsky, A.M., Rovinsky, A.B. Turing structures in the ferroin-catalyzed bromate oscilating system. React Kinet Catal Lett 42, 201–215 (1990). https://doi.org/10.1007/BF02065356
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DOI: https://doi.org/10.1007/BF02065356