Abstract
Kinetics of bromination of anisole by N-bromosuccinimide (NBS) has been investigated in 50 vol.% aqueous acetic acid. The reaction is first order in NBS and zero order in anisole. The reaction is of the ion-dipole type and NBS itself is the brominating agent.
Abstract
Кинетика бромирования анизола N-бромосукцинимидом (NBS) была исследована в 50 объем.%-ой водной уксусной кислоте. Реакция имеет первый порядок по NBS и нулевой порядок по анизолу. Реакция относится к ион-дипольному типу и было показано, что сам NBS является бромирующим реагентом.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
N. Venkatasubramanian, V. Thiagarajan: Tetrahedron lett.,35, 3349 (1967), Can. J. Chem.,47, 4, (1969).
V. Thiagarajan, N. Venkatasubramanian: Indian J. Chem.,8, 809 (1970).
N. S. Srinivasan, N. Venkatasubramanian: Indian J. Chem.,10, 1014 (1972).
P. S. Radhakrishnamurti, S. N. Sahu: Indian J. Chem.,15A, 785 (1977).
S. P. Mushran, J. N. Tiwari, A. K. Bose, K. Singh: Indian J. Chem.,16A, 35 (1978).
K. Singh, L. Pandey, S. P. Mushran: Indian J. Chem.,16A, 875 (1978).
N. Joseph, N. S. Gnanapragasam: Indian J. Chem.,19A, 653 (1980), and references therein.
K. J. P. Orton, A. E. Bradfield: J. Chem. Soc., 986 (1927).
C. Srinivasan, P. Kuthalingam, N. Arumugam: J. C. S. Perkin, II, 170 (1980).
R. C. Petersen, J. H. Markgraf, S. D. Ross: J. Amer. Chem. Soc.,83, 3819 (1961).
P. S. Radhakrishnamurti, B. Sahu: Indian J. Chem.,17A, 63 (1979).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Srinivasan, C., Chellamani, A. Kinetics and mechanism of bromination of anisole by N-bromosuccinimide. React Kinet Catal Lett 18, 187–191 (1982). https://doi.org/10.1007/BF02065161
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02065161