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Oscillatory behavior in the reaction of 3-alizarin-sulfonic acid sodium salt with acidic bromate

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Abstract

Uncatalyzed and catalyzed oscillatory behavior in the redox potential in the oxidation of 3-alizarin-sulfonic acid sodium salt with acidid (H2SO4) bromate is reported. Optimum and boundary conditions for each reactant exhibiting oscillatory behavior have been studied and a probable mechanism is suggested.

Abstract

Сообщается некатализированная и кататлизированная осцилляшия окислительно-восстановительных потенциалов в окислении натриевой соли 3-ализаринсульфо-новой кислоты кислым (H2SO4) броматом. Были исследованы оптимальные и граничные условия для каждого реагента, обнаруживающего осциллирующее поведение и предложен вероятный механизм.

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Authors and Affiliations

  1. School of Studies in Chemistry, Vikram University Ujjain, 456 010, India

    V. K. Gupta, P. K. R. Nair & K. Srinivasulu

Authors
  1. V. K. Gupta
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  2. P. K. R. Nair
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  3. K. Srinivasulu
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Gupta, V.K., Nair, P.K.R. & Srinivasulu, K. Oscillatory behavior in the reaction of 3-alizarin-sulfonic acid sodium salt with acidic bromate. React Kinet Catal Lett 18, 45–49 (1982). https://doi.org/10.1007/BF02065135

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  • DOI: https://doi.org/10.1007/BF02065135

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