Abstract
The kinetics of oxidation of methanol by chlorine dioxide has been investigated at 35 °C. The reaction is first order with respect to both substrate and chlorine dioxide. Molecular chlorine dioxide is the principal oxidant. The influence of various factors, e.g. ionic strength, inorganic salts, D2O and temperature on the initial rate has been studied. The activation parameters have been calculated and a mechanism involving hydride abstraction has been suggested.
Abstract
Кинетика окисления метанола двуокисью хлора была исследована при 35 °C. Реакция имеет первый порядок как по субстрату, так и по двуокиси хлора. Молекулярная двуокись хлора является принципиальным окислителем. Было изучено влияние различных факторов, напр. ионной силы, неорганических солей, D2O и температуры, на начальную скорость. Были рассчитаны параметры активации и предлагается механизм, вклющий перенос гидрида.
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Sharma, C.B. Kinetics of oxidation of methanol by chlorine dioxide. React Kinet Catal Lett 19, 167–173 (1982). https://doi.org/10.1007/BF02065079
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DOI: https://doi.org/10.1007/BF02065079