Advertisement

Reaction Kinetics and Catalysis Letters

, Volume 19, Issue 1–2, pp 155–160 | Cite as

Benzene hydrogenation on nickel/honeycomb catalysts

  • A. Parmaliana
  • A. Mezzapica
  • C. Crisafulli
  • S. Galvagno
  • R. Maggiore
  • N. Giordano
Article

Abstract

Monolithic supported nickel catalysts were investigated in benzene hydrogenation between 100 and 280 °C. The conversion of benzene to cyclohexane reaches a maximum around 210 °C with a maximum yield at a ratio poH2/poBz=3. The experimental results and some kinetic aspects are discussed.

Keywords

Hydrogenation Physical Chemistry Nickel Benzene Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Активность монолитнЫх никелевЫх катализаторов на носителяя бЫла исследована в гидрировании бензола при температурах от 100 до 280 °C. Конверсия бензола в циклогексан достигает максимума при приблизительно 210 °C с макси малянЫм вЫходом при отношении poH2/poB=3. Обсуждаются экспериментальнЫе результатЫ и некоторЫе кинетические аспектЫ.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. Parmaliana, C. Crisafulli, R. Maggiore, J. C. J. Bart, N. Giordano: React. Kinet. Catal. Lett.,18, 295 (1981).Google Scholar
  2. 2.
    R. Z. C. Van Meerten, J. W. E. Coenen: J. Catal.,37, 37 (1975).Google Scholar
  3. 3.
    J. E. Germain, R. Maurel, Y. Bourgeois, R. Sinn: J. Chem. Phys.,60 1219 (1963).Google Scholar
  4. 4.
    N. E. Zlotina, S. L. Kiperman: Kinet. Katal.,8, 393 (1967).Google Scholar
  5. 5.
    J. K. Marangozis, B. G. Mantzouranis, A. N. Sophos: Ind. Eng. Chem. Prod. Res. Dev.,18, 61 (1979).Google Scholar
  6. 6.
    J. Nicolai, R. Martin, J. C. Jungers: Bull. Soc. Chim. Belg.,57, 555 (1948).Google Scholar
  7. 7.
    H. A. Franco, M. J. Phillips: J. Catal.,63, 346 (1980).Google Scholar

Copyright information

© Akadémiai Kiadó 1982

Authors and Affiliations

  • A. Parmaliana
    • 1
  • A. Mezzapica
    • 1
  • C. Crisafulli
    • 2
  • S. Galvagno
    • 1
  • R. Maggiore
    • 2
  • N. Giordano
    • 1
  1. 1.Istituto CNR-Via S. Lucia sopra ContesseMessinaItaly
  2. 2.Istituto Dipartimentale di Chimica e Chimica IndustrialeLaboratorio Petrolchimica Università di CataniaCataniaItaly

Personalised recommendations