Abstract
Studies of the initial step of liquid-phase oxidation of 8-pentadecanone catalyzed by chromium stearate (CrSt3) indicate that the catalyst takes part in the formation of free radicals in the interaction of ketone with dissolved oxygen. In chain propagation and termination reactions CrSt3 does not participate.
Abstract
Изучена начальная стадия катализированного стеаратом хрома (CrSt3) окисления 8-пентадеканона. Установлено, что катализатор принимает участие в образовании свободных радикалов при взаимодействии с кетоном и растворённым кислородом. В реакциях продолжения и обрыва цепей CrSt3 практически не участвует.
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Dmitrieva, O.P., Agabekov, V.E. & Mitskevich, N.I. Kinetic peculiarities of 8-pentadecanone in the presence of chromium stearate. React Kinet Catal Lett 19, 139–143 (1982). https://doi.org/10.1007/BF02065074
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DOI: https://doi.org/10.1007/BF02065074