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Induction period of the conversion of methanol to hydrocarbons on a nickel loaded faujasite: Evidence for a suppression of the autocatalytic step

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Abstract

The conversion of methanol to hydrocarbons on nickel loaded faujasites can be retarded for many hours time-on-stream. The induction period is interpreted to be due to a suppression of the autocatalytic step of the reaction. An autocatalytic mechanism is proposed based on the β-scission of branched carbenium ion intermediates.

Abstract

Превращение метанола в утлеводороды на фаучэитах с загрузками никеля бчло замедлено на несколвко часов во времени ра потоке. Индукционный период обвяснялся подавлением автокаталитическй ступени реакции. Предлагается звтокаталитический механизм, основанный нс β-расзеплении разветвленных промежуточных ионов карбения.

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Authors and Affiliations

  1. Research Group Applied Catalysis Department of Chemistry, University of Bremen, D-2800, Bremen, FRG

    N. Jaeger, A. Jahn & G. Schulz-Ekloff

Authors
  1. N. Jaeger
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  2. A. Jahn
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  3. G. Schulz-Ekloff
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Jaeger, N., Jahn, A. & Schulz-Ekloff, G. Induction period of the conversion of methanol to hydrocarbons on a nickel loaded faujasite: Evidence for a suppression of the autocatalytic step. React Kinet Catal Lett 19, 79–83 (1982). https://doi.org/10.1007/BF02065062

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  • DOI: https://doi.org/10.1007/BF02065062

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