Abstract
A quantitative allowance for the solvation corrections fsolv eliminates deviations from the Brönsted lines for the bases OH−, H2O, and primary and secondary amines and straightens these lines for known base-catalysed reactions.
Abstract
Количественный учёт сольватационных поправок fsolv устраняет отклонения от линий Бренстеда для оснований OH−, H2O, первичньх и вторичных аминов и спрямляет зти линии для известных реакций основного катализа.
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Rudakov, E.S., Pryadko, A.F. & Lobachev, V.L. Solvation corrections to the Brönsted equation for general base catalysis. React Kinet Catal Lett 19, 55–59 (1982). https://doi.org/10.1007/BF02065057
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DOI: https://doi.org/10.1007/BF02065057