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Influence of preparation conditions on activity and stability of catalysts for 3-thiolene-1, 1-dioxide hydrogenation

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Abstract

Dispersity of γ-Al2O3-supported palladium and activity and selectivity of these catalysts in hydrogenation of 3-thiolene-1,1-dioxide to thiolane-1,1-dioxide have been found to be dependent on the composition of impregnating solutions and the additional chemical treatment prior to reduction. This effect is due to the changes in Pd2+ mobility over the support surface.

Abstract

Дисперсность нанесенного на γ-Al2O3 палладия, активность и устойчивость катализаторов в реакции гидрирования 3-тиолен-1,1-диоксида в тиолан-1,1-диоксид существенно зависят от состава пропиточного раствора и дополнительной перед восстановлением химической обработки. Это влияние определяется изменением подвижности иона Pd2+ по поверхности носителя.

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References

  1. A.V. Mashkina, N.T. Kulishkin, V.P. Kornilova: Kinet. Katal.,16, 697 (1975).

    Google Scholar 

  2. N.T. Kulishkin, A.V. Mashkina, N.E. Buyanova, A.P. Karnaukhov, I.D. Ratner, L.M. Plyasova: Kinet. Katal.,12, 539 (1971)

    Google Scholar 

  3. Yu.A. Savostin, N.T. Kulishkin, A.V. Mashkina: in Catalysts for Production and Conversion of Sulforous Compounds. Novosibirsk, Inst. Catal., 1979, p. 62.

    Google Scholar 

  4. N.T. Kulishkin, A.V. Mashkina, N.E. Buyanova: Kinet. Katal.,14, 1068 (1973).

    Google Scholar 

  5. A.P. Karnaukhov: Kinet.Katal., 1520 (1971)

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Authors and Affiliations

  1. Technological Institute of Food Industry, Kemerovo

    N. T. Kulishkin

  2. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. V. Mashkina

Authors
  1. N. T. Kulishkin
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  2. A. V. Mashkina
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Kulishkin, N.T., Mashkina, A.V. Influence of preparation conditions on activity and stability of catalysts for 3-thiolene-1, 1-dioxide hydrogenation. React Kinet Catal Lett 43, 527–531 (1991). https://doi.org/10.1007/BF02064723

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  • DOI: https://doi.org/10.1007/BF02064723

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