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Catalytic conversion of 2-propanol on cation-substituted forms of oxidized carbon

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Abstract

A series of cation-substituted forms of oxidized carbon has been prepared and the catalytic activity tested for 2-propanol decomposition. It was found that the carbons promote both dehydration and dehydrogenation of the alcohol. The products are propene, diisopropyl ether, and acetone, respectively. The cation exchange enhances the dehydrogenation activity at the expense of the dehydration activity.

Abstract

Получен ряд катионнозамещенных форм окисленного угля, каталитическую активность которого тестировали в разложении пропан-2-ола. Угли промотируют как дегидрата-цию, так и дегидрогенизацию спирта. Продуктами явля-ются пропен, диизопропиловый эфир и ацетон, соответ-ственно. Катионный обмен повышает активность к дегидрогенизации за счет дегидратации.

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Authors and Affiliations

  1. Institute of Chemistry, N. Copernicus University, Gagarina 7, 87-100, Toruń, Poland

    G. S. Szymański & G. Rychlicki

Authors
  1. G. S. Szymański
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  2. G. Rychlicki
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Szymański, G.S., Rychlicki, G. Catalytic conversion of 2-propanol on cation-substituted forms of oxidized carbon. React Kinet Catal Lett 43, 475–479 (1991). https://doi.org/10.1007/BF02064715

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  • DOI: https://doi.org/10.1007/BF02064715

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