Skip to main content
SpringerLink
Log in

Nature of catalytic effect of Ni(O)- and BF3OEt2-based systems in propene dimerization

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

1H NMR, EPR and IR spectroscopic studies of the products of the interaction between components of the Ni[PPh3]4+EtOH+BF3.OEt2 and Ni(PPh3)4+BF3OEt2 systems suggest the formation of two types of complexes [HNi(PP3)3L]+[BF3OEt]− and [Ni(PPh3)3L]+BF −4 , which are catalytically active in propene dimerization.

Abstract

На основании данных ЯМР1H, ЭПР, ИК-спектроскопии продуктов взаимодействия компонентов системы Ni(PPh3)4+ EtOH+BF3OEt2 и Ni(PPh3)4+BF3·OEt2 сделан вывод о формировании двух типов комплексов [HNi (PPh3)3L]+ [BF3OEt]− и [Ni (PPh3)L2]+BF −4 активных в димеризации пропилена.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V.S. Tkach, L.V. Mironova, N.D. Malakhova, N.A. Chuikova, F.K. Shmidt: Basic Organic Synthesis and Oil Chemistry, Collected Papers of Yaroslavl' Institutes, Vol. 6, p. 6, 1976.

    Google Scholar 

  2. USSR Pat. 599, 835. V.S. Tkatch, F.K. Shmidt, A.V. Kalabina, L.V. Mironova, N.D. Malakhova, N.A. Chuikova, Bull. Izobret. 2, 1978.

  3. F.K. Shmidt, L.V. Mironova, G.A. Kalabin, G.V. Ratovskii, A.G. Proidakov, T.V. Dmitrieva: Kinet. Katal.,19, 150 (1978)

    Google Scholar 

  4. V.V. Saraev, F.K. Shmidt, G.M. Larin, V.S. Tkach, V.G. Lipovich: Koord. Khim.,1, 1352 (1975)

    Google Scholar 

  5. V.S. Tkach, F.K. Shmidt, T.V. Dmitrieva, G.V. Ratovskii, N.D. Malakhova, M.M. Murasheva, Gomboogiin Myagmarsuren: Koord. Khim.,14, 1424 (1988)

    Google Scholar 

  6. A. Tkač, A. Stasko: Coll. Czech. Chem. Commun.,37, 573 (1972)

    Google Scholar 

  7. T. V. Dmitrieva, G. V. Ratovskii, N. A. Murasheva, V. S. Tkach, F. K. Shmidt: Proc. 4th All-Union Conf. on Organometal. Chemistry (Abstracts), Kazan, pp. 3 and 52, 1988.

  8. F.X. Cai, C. Lepetit, M. Kermarec, D. Olivier: J: Mol. Catal.,43, 93 (1988)

    Google Scholar 

  9. H. Bonneman: Angew. Chem.,82, 699 (1970)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Gomboogiin Myagmarsuren, T.V. Dmitrieva, G. V., Ratovskii

    V. A. Tkach, V. A. Gruznykh & N. A. Murasheva

  2. Irkutsk State University, 664003, Irkutsk, USSR

    S. V. Zinchenko & F. K. Shmidt

Authors
  1. V. A. Tkach
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Gruznykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Murasheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Zinchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. K. Shmidt
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tkach, V.A., Gruznykh, V.A., Murasheva, N.A. et al. Nature of catalytic effect of Ni(O)- and BF3OEt2-based systems in propene dimerization. React Kinet Catal Lett 43, 431–437 (1991). https://doi.org/10.1007/BF02064709

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02064709

Keywords

Search

Navigation