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Reaction Kinetics and Catalysis Letters

, Volume 43, Issue 2, pp 425–430 | Cite as

Catalytic effect of hydroxy groups on reaction of polyamine with tert-butyl acrylate

  • J. Švachula
  • J. Horálek
Article

Abstract

The reaction of N-cyclohexyl-1,3-propanediamine with tert-butyl acrylate and the catalytic effect of hydroxy groups on the reaction course was investigated by Near Infrared spectroscopy. The reaction was found to be bimolecular and of second order. The dependence of rate constant on catalyst concentration (diols) is linear and the structure of diol used has no effect.

Keywords

Spectroscopy Physical Chemistry Catalysis Infrared Spectroscopy Acrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Исследовали реакцию N-циклогексил-1,3-пропандиамина с трет-бутилакрилатом. Каталитический эффект гидроксильных групп на ход реакции исследовали с помощью Близкой Инфракрасной Спектроскопии. Реакция бимолекулярна и имеет второй поядок. Зависимость константы скорости от концентрации катализатора (диола) линейна, а структура диола не оказывает никакого зффекта.

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References

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Copyright information

© Akadémiai Kiadó 1991

Authors and Affiliations

  • J. Švachula
    • 1
  • J. Horálek
    • 2
  1. 1.Institute of Chemical TechnologyPardubiceČSFR
  2. 2.Research Institute of Synthetic Resins and LacquersPardubiceČSFR

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