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Hydroxylation selectivity of phenol and O-protected phenols in the Fe(III)-catechol-H2O2 system

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Abstract

Oxidation selectivity of phenol and its O-protected derivatives in the Hamilton system has been studied. Modification of OH groups by acyl substituents and addition of β-cyclodextrin markedly enhance paraselectivity of this reaction.

Abstract

Изучена селективность окисления фенола и его O-защищенных производных в системе Гамильтона. Установлено, что модификация OH-группы ацильными заместителями и добавка β-циклодекстрина значительно увеличивают пара-селективность реакции.

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Authors and Affiliations

  1. Chemical Enzymology Department, Chemistry Faculty, Moscow State University, 117234, Moscow, USSR

    A. V. Eliseev & A. K. Yatsimirskii

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  1. A. V. Eliseev
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  2. A. K. Yatsimirskii
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Eliseev, A.V., Yatsimirskii, A.K. Hydroxylation selectivity of phenol and O-protected phenols in the Fe(III)-catechol-H2O2 system. React Kinet Catal Lett 43, 419–423 (1991). https://doi.org/10.1007/BF02064707

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  • DOI: https://doi.org/10.1007/BF02064707

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