Abstract
The difference in reactivity of PdCl 2−4 and PdBr 2−4 species versus the Al2O3 hydrous surface was explained according to the trans-effect theory. It has important consequences on Pd uptake rates and impregnation profiles.
Abstract
Различия в реактивности PdCl 2−4 и PdBr 2−4 к водным поверхностям Al2O3 объясняли на основе теории трансэффекта. Она позволяет делать важные заключения относительно скорости высаждения Pd и профилей импрегнирования.
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Conţescu, C., Vass, M.I. Impregnation of alumina with palladium tetrahalide anionic complexes. React Kinet Catal Lett 43, 393–398 (1991). https://doi.org/10.1007/BF02064703
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DOI: https://doi.org/10.1007/BF02064703