Abstract
Zeolite Y, partially dealuminated under hydrothermal conditions, is used as a support for nickel clusters. The effect of the zeolite structure and of the means of applying the Ni2+ cations on the reactivity of dispersed nickel in CO methanation has been studied. The highest conversion was obtained on samples with developed secondary porosity, impregnated with the nickel ammine complex, [Ni(H2O)2 (NH3)4]Cl2. The data obtained are discussed from the point of view of the effect of secondary porosity and the means of introducing the parent Ni2+ ions on the localization and thermal stability of Nio clusters.
Abstract
В гидротермических условиях деалюминированный цеолит У был использован как носитель кластеров никеля. Исследовали влияние текстуры цеолита и метода внесения Ni2+ в цеолит на реактивность диспергированного Nio в реакции восстановления CO. Самая высокая конверсия была достигнута на образцах с развитой вторичной пористостью, импрегнированных аммокомплексом Ni, [Ni(H2O)2(NH3)4]Cl2. Результаты обсуждают, исходя из влияния вторичной пористости на локализацию и термическую стабильность кластеров.
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Pospíšil, J., Drahorádová, E. Effect of zeolite support on catalytic activity of Nio clusters. React Kinet Catal Lett 43, 367–373 (1991). https://doi.org/10.1007/BF02064699
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DOI: https://doi.org/10.1007/BF02064699