Abstract
Studies of kinetic peculiarities in hydroxylation of phenols by H2O2 in the presence of ferric sulfate have revealed general regularities of this process. A scheme of this process is suggested accounting for the stepwise conversion of Fe3+ into various complex forms. The reaction is suggested to take place in the coordination sphere of Fe3+.
Abstract
Исследованы кинетические зависимости реакции гидроксилирования фенолов H2O2 в присутствии сульфата желиза. Выявлены общие закономерности этого процесса. На основании полученных данных предложена схема его протекания, учитываущая постадийный переход Fe3+ в различные комплексные формы.
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Mitnik, Y.V., Oludipe, D.O., Litvintsev, I.Y. et al. Catalytic oxidation of monosubstituted phenols by hydrogen peroxide. React Kinet Catal Lett 43, 321–328 (1991). https://doi.org/10.1007/BF02064692
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DOI: https://doi.org/10.1007/BF02064692