Reaction Kinetics and Catalysis Letters

, Volume 43, Issue 2, pp 293–299 | Cite as

Adsorbate interaction between carbon monoxide and ethylene over γ-Al2O3

  • Takashi Suzuki
  • Toshihiro Hirai
  • Sadao Hayashi


CO and/or ethylene adsorbed on γ-Al2O3 was subjected to temperature programmed desorption (TPD). When temperature of the gas adsorbed specimens was linearly raised, two peaks were observed in desorption profile of both ethylene and that of CO. When an equimolecular misture of carbon monoxide and ethylene was adsorbed over the specimen, desorption temperature of CO(H) shifted to high temperature side of 87.2 °C, whereas that of ethylene (H) shifted to low temperature side of 33.0 °C. This behavior of desorption temperature might be attributed to a strong interaction in the two adsorbates induced by an electronic effect.


Ethylene Physical Chemistry Catalysis Carbon Monoxide Strong Interaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Адсорбцию CO и/или этилена на γ-Al2O3 исследовали с помощью ТПД. При линейном повышении температуры наблюдали два пика в десорбционных профилях, характерных для этилена и CO. В случае адсорбции эквимолярной смеси моноокиси углерода и этилена температура десорбции CO(H) сдвигалась в направлении более высоких температур (87, 2°C), а этилена (H) в направлении более низких температур (33°C). Это объясняли, исходя из сильных взаимодействий между двумя адсорбатами за счет электронных эффектов.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    A. Verma, D. M. Ruthven: J. Catal.,46, 160 (1977).Google Scholar
  2. 2.
    A. Blenner, D. A. Hucul, S. J. Hardwick: Inorg. Chem.,18, 1478 (1979).Google Scholar
  3. 3.
    J. Savkany, R. D. Gonzalez: J. Catal.,76, 75 (1982).Google Scholar
  4. 4.
    B. Jóvér, J. Juhász, Z. G. Szabó: Appl. Catal.,5, 291 (1983).Google Scholar
  5. 5.
    A. Zecchina, G. Spoto, E. Borello, E. Giamello: J. Phys. Chem.,88, 2585 (1984).Google Scholar
  6. 6.
    H. Hattori, H. Imai, H. Itoh: Chem. Lett., 1311 (1981).Google Scholar
  7. 7.
    J. T. Kiss, R. D. Gonzalez: J. Phys. Chem.,88, 842 (1984).Google Scholar
  8. 8.
    J. T. Kiss, R. D. Gonzalez: J. Phys. Chem.,88, 898 (1984).Google Scholar
  9. 9.
    T. Suzuki, S. Hayashi, T. Hirai, K. Tanaka, I. Toyoshima: J. Mol. Catal.,49, 43 (1989).Google Scholar

Copyright information

© Akadémiai Kiadó 1991

Authors and Affiliations

  • Takashi Suzuki
    • 1
  • Toshihiro Hirai
    • 1
  • Sadao Hayashi
    • 1
  1. 1.Department of Chemistry, Faculty of Textile Science and TechnologyShinshu UniversityNaganoJapan

Personalised recommendations