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Kinetic studies of pyridine catalyzed alkanesulfornylation of phenols

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Abstract

Kinetic studies of the pyridine catalyzed reaction between phenylmethanesulfochloride and phenols in non-aqueous media have provided quantitative estimates for the effect of reactant structure, catalyst and reaction medium polarity on competing reaction routes. For the first time a “sulfene” mechanism in pyridine catalyzed processes of alkanesulfonyl transport has been discovered. Criteria for its realization are suggested.

Abstract

Изучена кинетика катализируемой пиридинами реакции фенилметансульфохлорида с фенолами в неводных средах. количественно оценено влияние строения рергента, катализатора и полярности среды на конкурирующие маршруты реакции. Впервые обнаружен “сульфеновый” механизм в катализируемых пиридинами процессах алкансульфонильного транспорта и определены критерии его реализации.

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References

  1. K. Tinnius: Plasticizers. Khimiya, Moskva 1964.

    Google Scholar 

  2. L.M. Litvinenko, N.M. Oleinik: Mechanisms of Catalytic Action of Organic Catalysts. Basic and Nucleophilic Catalysis. Naukova Dumka, Kiev 1984.

    Google Scholar 

  3. Yu.G. Skryupnik, V.P. Bezrodnyi: Dokl. Akad. Nauk SSSR,266, 642 (1982).

    Google Scholar 

  4. Yu.G. Skrypnik, V.P. Bezrodnyi, S.N. Baranov: Phosph. Sulfur,6, 285 (1979).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Organic and Coal Chemistry, 340114, Donetsk, USSR

    Yu. G. Skrypnik & S. N. Lyashchuk

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  1. Yu. G. Skrypnik
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  2. S. N. Lyashchuk
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Skrypnik, Y.G., Lyashchuk, S.N. Kinetic studies of pyridine catalyzed alkanesulfornylation of phenols. React Kinet Catal Lett 43, 283–288 (1991). https://doi.org/10.1007/BF02064686

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  • DOI: https://doi.org/10.1007/BF02064686

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