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Activation of carbon monoxide on metal clusters. Extended Hückel molecular orbital model calculations

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Abstract

The binding energy of CO on Rh is greater than that on Co. The difference in binding energy arises from the destabilization of the s band of Co following CO adsorption. Binding energies of CO on metals of Fe, Ni, Cu and Rh have been compared.

Abstract

Энергия связи CO с Rh больше, чем с Co. Различия в энергии связи вызваны дестабилизацией ѕ полосы Co с последующей адсорбцией CO. Сравниваются энергии связи CO с металлами Fe, Ni, Cu и Rh.

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 600 036, Madras, India

    B. Viswanathan & Latha Swaminathan

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  1. B. Viswanathan
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  2. Latha Swaminathan
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Viswanathan, B., Swaminathan, L. Activation of carbon monoxide on metal clusters. Extended Hückel molecular orbital model calculations. React Kinet Catal Lett 25, 339–344 (1984). https://doi.org/10.1007/BF02064427

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  • DOI: https://doi.org/10.1007/BF02064427

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