Abstract
The problem of predicting the activity of oxide and carbonate catalysts for some reactions of petrochemical synthesis (vapor phase conversion of carboxylic acids, catalytic oxidation of asphaltic tar to bitumen) according to the established dependence of thermal stability variations of intermediates on the formation enthalpy of metal oxides or standard ele.trode potentials is discussed.
Abstract
В работе представлены материалы, связанные с прогнозированием активности оксидных и карбонатных катализаторов некоторых процессов нефтехимнческого синтеза (парофазная конверсия карбоновых кнслот, каталнтнческое окисление гудронов до битума) по обнаруженной зависимости изменения термоустойчивости промежуточно образуемых соединений от энтальпий образования окислов металлов или стандартных электродных потенциалов.
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References
R. N. Khlestkin, V. L. Khlestkina, N. G. Usanov, V. M. Gareev: Khim. Prom-st,7 391 (1982).
R. N. Khlestkin, V. L. Khlestkina, R. B. Valitov, N. G. Usanov: React Kinet. Catal. Lett.,17, 391 (1981).
R. B. Gun: Oil Bitumens, Khimilya, Moskva 1973.
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Khlestkin, R.N., Khlestkina, V.L., Gareev, V.M. et al. On the problem of predicting the activity of oxide and carbonate catalysts in some reactions of petrochemical synthesis. React Kinet Catal Lett 25, 289–291 (1984). https://doi.org/10.1007/BF02064417
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DOI: https://doi.org/10.1007/BF02064417