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Decomposition of n-pentadecyl hydroperoxides in the presence of nickel and cerium stearates

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Abstract

Overall and radical decompositions of n-pentadecyl hydroperoxides by nickel and cerium stearates have been studied. Reaction orders, effective activation energies, rate constants for the overall decompostion and radical formation have been calculated.

Abstract

Изучены брутто-и радикальный распад гидропероксидов n-пентадецила в присутствии стеаратов никеля и церия. Определены порядки реакций, эффективные энергии активации, константы скорости брутто-разложения и радикалообразования.

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, Minsk, USSR

    S. V. Krylova, M. N. Fedorischeva, V. E. Agabekov & N. I. Mitskevich

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  1. S. V. Krylova
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  2. M. N. Fedorischeva
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  3. V. E. Agabekov
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  4. N. I. Mitskevich
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Krylova, S.V., Fedorischeva, M.N., Agabekov, V.E. et al. Decomposition of n-pentadecyl hydroperoxides in the presence of nickel and cerium stearates. React Kinet Catal Lett 25, 283–288 (1984). https://doi.org/10.1007/BF02064416

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  • DOI: https://doi.org/10.1007/BF02064416

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