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Influence of the chemical composition of the catalyst on the dehydrochlorination of 1,2-dichloroethane

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Abstract

The experiments have been performed by a microreactor pulse method at 623 K. The activity and selectivity of the catalysts, alumina/metal chloride and silica gel/metal chloride or oxide, have been found to depend on the donor-acceptor properties of their surfaces.

Abstract

Было исследовано влияние химического состава катализатора на его активность и селективность в дегидрохлорировании 1,2-дихлорзтана. Эксперименты производились в микрореакторе импульсным методом при 623 К. Активность и селективность катализаторов типа окись алюминия/хлорид металла и силикагель/хлорид или окись металла, зависят от акцепторнодонорных свойств их поверхности.

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References

  1. I. Mochida, J. Take., Y. Saito, Y. Yoneda: J. Org. Chem.,32, 3894 (1967).

    Google Scholar 

  2. M. F. Magier, N. G. Guseynov, T. A. Gadzhiev., T. N. Shakhtakhtinski: Azerb. Khim. Zh.41, 45 (1964);42, 103 (1965).

    Google Scholar 

  3. M. Misono: J. Catal.,30, 226 (1973).

    Google Scholar 

  4. H. Noller, P. Andreu, M. Hunger: Angew. Chem.,83, 185 (1971).

    Google Scholar 

  5. I. P. Pinionov, R. M. Flid, J. A. Trager: Zh. Fiz. Khim.,42, 2344 (1968).

    Google Scholar 

  6. I. Mochida, Y. Anju, H. Yamamoto, A. Kato, T. Seiyma: Bull. Chem. Soc. Japan,44, 3305 (1971).

    Google Scholar 

  7. R. B. Valitov, B. E. Prusenko, R. V. Khalitov, A. I. Ikhsanov, A. I. Selezniev, G. M. Panczenkov: Zh. Prikl. Khim.,49, 2053 (1976).

    Google Scholar 

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Czarny, Z., Oszczudlowski, J. Influence of the chemical composition of the catalyst on the dehydrochlorination of 1,2-dichloroethane. React Kinet Catal Lett 25, 195–199 (1984). https://doi.org/10.1007/BF02064400

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  • DOI: https://doi.org/10.1007/BF02064400

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