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Partial hydrogenation of benzene over platinum supported catalysts

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Abstract

Partial hydrogenation of benzene to cyclohexene has been studied on Pt/Nylon 66, Pt/MgO and Pt/TiO2. An effect of the support on the selectivity to cyclohexene was observed, Pt/Nylon showing the highest selectivity, followed by Pt/MgO and Pt/TiO2. An interaction of platinum with the more basic supports (Nylon, MgO) and a pretreatment under oxidizing conditions, results in a higher selectivity to cyclohexene.

Abstract

Частичное гидрирование бензола до циклогексена было исследовано на Pt/найлон 66, Pt/MgO и PtTiO2. Наблюдалось влияние носителя на селективность к образованию циклогексена, причем наивысшей селективностью обладала Pt/найлон, с последующими Pt/MgO и Pt/T,O2. Взаимодействие платины с более основными носителями (найлон, MgO) и предварительная обработка в окисляющих условиях приводят к высокой селективности к циклогексену.

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Authors and Affiliations

  1. Istituto CNR, Transformazione e Accumulo Energia, Via S. Lucia sopra Contesse 39, 98013, Pistunina, Messina, Italy

    P. Staiti, S. Galvagno, P. Antonucci & A. Rositani

  2. Istituto di Chimica Industriale, Universitá di Messina, Via dei Verdi, 98100, Messina, Italy

    P. Vitarelli

Authors
  1. P. Staiti
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  2. S. Galvagno
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  3. P. Antonucci
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  4. A. Rositani
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  5. P. Vitarelli
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Staiti, P., Galvagno, S., Antonucci, P. et al. Partial hydrogenation of benzene over platinum supported catalysts. React Kinet Catal Lett 26, 111–116 (1984). https://doi.org/10.1007/BF02063875

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  • DOI: https://doi.org/10.1007/BF02063875

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