Skip to main content
SpringerLink
Log in

Effect of the nature of carrier on dinitrogen fixation by supported titanium complexes

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Cyclopentadienyltitanium (IV) complexes supported on Al2O3, SiO2 and MgO reduced with BuLi were tested in dinitrogen fixation at room temperature under normal pressure. Only the system supported on Al2O3 is active in this reaction.

Abstract

Комплексы циклопентадиенил-титана (IV), нанесенные на Al2O3, SiO2 и MgO, восстановленные BuLi, тестировали в фиксировании азота при комнатной температуре и при нормальном давлении. Активными оказались лишь системы на Al2O3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. New Trends in the Chemistry of Nitrogen Fixation, J. Chatt ed. Academic Press 1980.

  2. J. Kijeński, R. Hombek, S. Malinowski: J.Catal.,50, 186 (1977)

    Google Scholar 

  3. J.E. Wentz, J.R. Bolton: Electron Spin Resonance, McGraw Hill, New York 1972.

    Google Scholar 

  4. M.E. Volpin, V.B. Shur: in “Organometallic Reactions”, Ed. E. Beclar, M. Tsutsui, p. 55. J. Wiley, New York 1970.

    Google Scholar 

  5. Chak Po Lau, Biaw Hung Chung, R.H. Grubbs, C.A. Brubaker: J.Organometal.Chem.,214, 325 (1981)

    Google Scholar 

  6. W. Skupiński, I. Ciešlowska-Glińska: J.Organometal.Chem., 269, 29 (1984)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Technology, Faculty of Chemistry, Technical University (Politechnika), Koszykowa 75, Warszawa, Poland

    W. Skupinski & W. Zyskowski

Authors
  1. W. Skupinski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. W. Zyskowski
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Skupinski, W., Zyskowski, W. Effect of the nature of carrier on dinitrogen fixation by supported titanium complexes. React Kinet Catal Lett 36, 479–483 (1988). https://doi.org/10.1007/BF02063851

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02063851

Keywords

Search

Navigation