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Reaction Kinetics and Catalysis Letters

, Volume 36, Issue 2, pp 479–483 | Cite as

Effect of the nature of carrier on dinitrogen fixation by supported titanium complexes

  • W. Skupinski
  • W. Zyskowski
Article

Abstract

Cyclopentadienyltitanium (IV) complexes supported on Al2O3, SiO2 and MgO reduced with BuLi were tested in dinitrogen fixation at room temperature under normal pressure. Only the system supported on Al2O3 is active in this reaction.

Keywords

Titanium Physical Chemistry SiO2 Al2O3 Catalysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Комплексы циклопентадиенил-титана (IV), нанесенные на Al2O3, SiO2 и MgO, восстановленные BuLi, тестировали в фиксировании азота при комнатной температуре и при нормальном давлении. Активными оказались лишь системы на Al2O3.

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Copyright information

© Akadémiai Kiadó 1988

Authors and Affiliations

  • W. Skupinski
    • 1
  • W. Zyskowski
    • 1
  1. 1.Institute of Organic Technology, Faculty of ChemistryTechnical University (Politechnika)WarszawaPoland

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