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Reaction Kinetics and Catalysis Letters

, Volume 36, Issue 2, pp 257–262 | Cite as

Formation mechanism and structure of compounds catalytically active in propylene dimerization and formed in Pd(acac)2−PR3−BF3OEt2 systems

  • V. S. Tkach
  • F. K. Schmidt
  • G. V. Ratovskii
  • N. D. Malakhova
  • N. A. Murasheva
  • M. L. Chernyshev
  • O. V. Burlakova
Article

Abstract

The interaction between the components of catalytic Pd(acac)2−PR3−BF3OEt2 systems dimerizing propylene to linear hexenes with 59 % selectivity, has been studied by UV and1H NMR spectroscopy methods. Formation mechanism of catalytically active [R3P−Pd−H]+BF 4 compounds is suggested.

Keywords

Spectroscopy Physical Chemistry Hexenes Catalysis Propylene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Методами УФ, ЯМР1Н спектроскопии изучено взаимодействие компонентов каталитических систем типа Pd(acac)2−PR3−BF3OEt2, димеризующих пропилен в линейные гексены с селективностью до 59%, предложен механизм образования каталитически активных комплексов типа [R3P−Pd−H]+BF 4 .

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References

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Copyright information

© Akadémiai Kiadó 1988

Authors and Affiliations

  • V. S. Tkach
    • 1
  • F. K. Schmidt
    • 1
  • G. V. Ratovskii
    • 1
  • N. D. Malakhova
    • 1
  • N. A. Murasheva
    • 1
  • M. L. Chernyshev
    • 1
  • O. V. Burlakova
    • 1
  1. 1.State UniversityIrkutskUSSR

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