Abstract
Uranium- and Th-series radionuclides have been analyzed in CO2-rich geothermal waters and their associated iron hydroxide and carbonate deposits from the French Massif Central. A geochemical budget for U and Ra in water and solid deposits has been estimated. Most of the U (>75%) remains in solution, probably because of the presence of soluble U-carbonate complexes. In contrast, a large fraction of Ra (>50%) is scavenged by both deposit types. The distribution coefficient of U and Ra in calcite are 0.2 and 0.4 respectively. The DRa value is much higher than the experimentally determined coefficients and represents a non-equilibrium value that might be applicable to natural systems with high CaCO3 precipitation rates.
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Rihs, S., Condomines, M. & Fouillac, C. U- and Th-series radionuclides in CO2-rich geothermal systems in the French Massif Central. J Radioanal Nucl Chem 226, 149–157 (1997). https://doi.org/10.1007/BF02063640
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DOI: https://doi.org/10.1007/BF02063640