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Temperature effects in the oxidation of aliphatic ketones by solutions of thallic sulfate

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Abstract

The oxidation of aliphatic ketones by thallium(III) sulfate in aqueous medium has been studied from the point of view of the temperature effect and the enthalpy-entropy relationship. It has been found that the isokinetic relationship is fulfilled in this case.

Abstract

Окисление алифатических кетонов сульфатом таллия(III) в водных средах было исследовано с точки эрения температурного эффекта и энтальпийно-энтропийной зависимости. Было найдено, что изокинетическая зависимость соблюдается в данном случае.

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References

  1. A. Meenakshi, M. Santappa: Indian. J. Chem.,11A, 393 (1973).

    Google Scholar 

  2. P. S. Radhakrishnamurti, S. N. Pati: Indian J. Chem.,17A, 97 (1979).

    Google Scholar 

  3. A. McKillop, D. W. Young, M. Edwards, R. P. Hug, E. C. Taylor: J. Org. Chem.,43, 3773 (1978).

    Google Scholar 

  4. M. Pechál, Z. Cvengrosová, M. Hrusovský: Chem. Prum.,31, 525 (1981).

    Google Scholar 

  5. M. Strasák, M. Hrusovský, J. Urbanec, J. Vojtko, S. Gregus: Chem. Zvesti,30, 553 (1976).

    Google Scholar 

  6. M. Marko, L. Krasnec: Fundamentals of Preparative Organic Chemistry, SNTL, Bratislava 1962 (in Slovak).

    Google Scholar 

  7. M. Pechál, J. Vojtko, J. Kubena, M. Hrusovský: React. Kinet. Catal. Lett.,20, 151 (1982).

    Google Scholar 

  8. O. Exner: Collect. Czech. Chem. Commun.,29, 1094 (1964).

    Google Scholar 

  9. O. Exner: Progr. Phys. Org. Chem.,10, 411 (1973).

    Google Scholar 

  10. D. A. Blackadder, C. Hinshelwood: J. Chem. Soc., 2720, 2728 (1958).

    Google Scholar 

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Authors and Affiliations

  1. Shoe and Leather Research Institute, 762 65, Gottwaldov, Czechosolovakia

    M. Pechál

  2. Department of Analytical Chemistry, Pharmaceutical Faculty, Comenius University, 880 34, Bratislava, Czechoslovakia

    M. Strasák

  3. Department of Organic Technology, Slovak Technical University, 880 37, Bratislava, Czechoslovakia

    J. Vojtko & M. Hrusovský

Authors
  1. M. Pechál
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  2. M. Strasák
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  3. J. Vojtko
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  4. M. Hrusovský
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Pechál, M., Strasák, M., Vojtko, J. et al. Temperature effects in the oxidation of aliphatic ketones by solutions of thallic sulfate. React Kinet Catal Lett 20, 157–161 (1982). https://doi.org/10.1007/BF02063602

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  • DOI: https://doi.org/10.1007/BF02063602

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