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Michael addition of nitromethane to 3-buten-2-one catalyzed by potassium fluoride supported on Al2O3, ZnO, SnO2, sepiolite, AlPO4, AlPO4−Al2O3 and AlPO4−ZnO

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Abstract

The Michael addition of nitromethane to 3-buten-2-one has been carried out in the absence of solvent, using potassium fluoride supported on Al2O3, ZnO, SnO2, sepiolite, AlPO4, AlPO4−Al2O3 and AlPO4−ZnO catalysts. We found that KF/ZnO easily performed the Michael addition and thus, ZnO is a better support for the basic reagent than Al2O3. Besides, the Michael addition was not successful with AlPO4 or AlPO4-metal oxide acidic supports.

Abstract

Михазлевское присоединение нитрометана к 3-бутен-2-ону проводили в отсутствии растворителя, используя в качестве катализатора фтористый калий, нанесенный на Al2O3, ZnO, SnO2, сепиолит, AlPO4, AlPO4−Al2O3 и AlPO4−ZnO. Найдено, что KF/ZnO легко проводит реакцию и т.о. ZnO, как основной реагент, является лучшим носителем, чем Al2O3. Помимо зтого, присоединение Михазля совсем не протекает на кислых носителях таких, как AlPO4 или AlPO4-окись металла.

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References

  1. J.H. Clark: Chem. Rev.,80, 429 (1980), and references therein.

    Google Scholar 

  2. J. Yamawaki, T. Kawate, T. Ando, T. Hanafusa: Bull. Chem. Soc. Jpn.,56, 1885 (1983).

    Google Scholar 

  3. J.M. Clark, D.G. Cork, M.S. Robertson: Chem. Lett., 1145 (1983).

  4. F. Texier-Boullet, D. Villemin, M. Ricard, H. Moison, A. Foucaud: Tetrahedron,41, 1259 (1985), and references therein.

    Google Scholar 

  5. J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas: Afinidad,39, 325 (1982).

    Google Scholar 

  6. J.A. Cabello, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas: J. Org. Chem.,51, 1786 (1986).

    Google Scholar 

  7. J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas: Reactiv. Solids,3, 263 (1987).

    Google Scholar 

  8. J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas: J. Catal.,111, 106 (1988).

    Google Scholar 

  9. J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, M.I. Martinez: Mater. Chem. Phys.,21, 409 (1989).

    Google Scholar 

  10. J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, M. Martinez-Cunquero: XI. Iberoamerican Symposium on Catalysis, Guanajuato, Mexico, 1988, p. 799.

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Authors and Affiliations

  1. Departamento Quimica Orgánica, Universidad de Córdoba, Avda. San Alberto Magno, s/no, E-14004, Cordoba, España

    J. M. Campelo, M. S. Climent & J. M. Marinas

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  1. J. M. Campelo
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  2. M. S. Climent
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  3. J. M. Marinas
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Campelo, J.M., Climent, M.S. & Marinas, J.M. Michael addition of nitromethane to 3-buten-2-one catalyzed by potassium fluoride supported on Al2O3, ZnO, SnO2, sepiolite, AlPO4, AlPO4−Al2O3 and AlPO4−ZnO. React Kinet Catal Lett 47, 7–11 (1992). https://doi.org/10.1007/BF02063553

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  • DOI: https://doi.org/10.1007/BF02063553

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