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Stability of manganese telluromolibdate, Mn3Mo2TeO12, during selective oxidation of toluene to benzaldehyde

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Abstract

Decomposition of Mn3Mo2TeO12 during oxidation of toluene to benzaldehyde was observed. Depending on the surface composition of the initial catalyst, the decomposition leads to less active but highly selective MnMoTeO6 or to MnMoO4 which is not selective in toluene oxidation.

Abstract

Наблюдалось разложение Mn3Mo2TeO12 в ходе окисления толуола до бензальдегида. В зависимости от состава поверхности исходного катализатора зто разложение приводит либо к менее активному, но более селективному MnMoTeO6, либо к совсем неселективному в окислении толуола MnMoO6.

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Authors and Affiliations

  1. Laboratoire de Catalyse Hétérogène et Homogène, Université des Sciences et Techniques de Lille Flandres Artois, C.N.R.S., U.R.A. n 402, 59655, Villeneuve D'Ascq, France

    Y. Barbaux, S. Dejonghe & L. Gengenbre

  2. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, 30-239, Kraków, Poland

    B. Grzybowska

Authors
  1. Y. Barbaux
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  2. S. Dejonghe
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  3. L. Gengenbre
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  4. B. Grzybowska
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Barbaux, Y., Dejonghe, S., Gengenbre, L. et al. Stability of manganese telluromolibdate, Mn3Mo2TeO12, during selective oxidation of toluene to benzaldehyde. React Kinet Catal Lett 47, 1–6 (1992). https://doi.org/10.1007/BF02063552

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  • DOI: https://doi.org/10.1007/BF02063552

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